Explanation
No. Microwave ovens do not generally cook food from its centre outward. Their waves deposit energy within the parts of the food they penetrate, rather than targeting the centre first.
The FDA explains that, in thick foods, microwaves primarily heat the outer layers while heat conduction helps cook the interior. Virginia Tech's food-science specialists also explicitly reject the inside-out description and explain that direct microwave penetration is limited.
Heating is not necessarily uniform. Food composition, size, shape and whether it is frozen affect the result. Producing heat within food is therefore different from heating every part equally or cooking the centre first.
Key takeaway
Microwaves generate heat within food, but that does not mean the centre heats first or the whole portion heats evenly.